Molecular Sieve- A Brief Introduction

Molecular Sieves are much in demand
due to their uniform pore crystalline structure. This added with their large
surface area speeds up the absorption process to a large extent. Molecular
Sieves work by using the size exclusion principle. When water molecules come in
contact with the Molecular Sieve, only those molecules which fit into the pores
are absorbed while the larger molecules pass through. The pore size of
Molecular Sieves are in the range of 3,4,5 and 10 Angstroms. When the
absorption process is going on depending on the pore size, the water molecules
will be absorbed or move forward. This is one of the biggest benefits of using
Molecular Sieves as desiccants for removing water vapour.
The main difference while using
Molecular Sieve and other desiccants like Silica Gel and Activated Alumina is
that in Molecular Sieves, the absorbed molecules get trapped while in the
others, the absorbed molecules are free to move away. This is why when
Molecular Sieves are used, the water molecules are retained in the pores,
freeing the remaining area of moisture.
Molecular Sieves pellets are widely
used in drying oil and liquid gas streams and solvent drying because this
desiccant can hold 22% of its own weight in water. Molecular Sieve beads also
witness much demand because their absorption qualities are much superior to
other desiccants. These qualities include adsorption possible based on
molecular size, molecular affinity for the sieve crystal surface and finally
the shape of the molecule.
Molecular Sieve Beads/Pellets in Solvent Drying

When the bottles containing the
solvents are opened, there are chances that they will pick up moisture from the
surroundings so that is why Molecular Sieves are used to dry up the solvents.
These dried solvents are used in the final stages of dehydration and embedding.
The solvent and the water will be quickly adsorbed onto the molecular sieve
surfaces as the small pores can only access the smaller water molecules.
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